Kinetic changes in cellulose properties during defibrillation into microfibrillated cellulose and cellulose nanofibrils by ultra-refining. (2019)
- Authors:
- USP affiliated authors: ARANTES, VALDEIR - EEL ; BERTO, GABRIELA LEILA - EEL
- Unidade: EEL
- DOI: 10.1016/j.ijbiomac.2019.01.169
- Subjects: CINÉTICA QUÍMICA; MATERIAIS NANOESTRUTURADOS
- Agências de fomento:
- Language: Inglês
- Abstract: Defibrillation of cellulose fibers can lead to the isolation of microfibrillated cellulose (MFC) or cellulose nanofibrils (CNF) with intrinsic properties suitable for various applications. However, to what extent these properties are preserved, enhanced, gained or lowered during defibrillation and how they are related remains unclear. In this study, a kinetic study of the ultra-refining of bleached eucalyptus Kraft pulp (BEKP) in a disc ultra-refiner was performed and characterized in terms of physical-structural, morphological and thermal properties and their interactions and compromises. Defibrillation of BEKP to MFC substantially decreased the fiber diameter and in- creased viscosity, surface area and morphological heterogeneity. It also led to a remarkable increase in transpar- ency and essentially did not alter the thermostability but significantly degraded the crystallinity. A higher degree of defibrillation to isolate CNF led to fibers with smaller diameter and increased diameter uniformity but required a substantial amount of energy to only marginally increase viscosity and transparency. Crystallinity and thermo- stability were not altered, comparing with CMF. In conclusion, most changes occurred during the defibrillation of BEKP to CMF. Further defibrillation to CNFs with smaller diameters and better uniformity did not significantly re- flect on other important structural cellulose physical properties, despite the much higher energy consumption and degree of defibrillation.
- Imprenta:
- Source:
- Título do periódico: International journal of biological macromolecules
- ISSN: 01418130
- Volume/Número/Paginação/Ano: v.127, n.15, p.637-648, 2019
- Este periódico é de assinatura
- Este artigo NÃO é de acesso aberto
- Cor do Acesso Aberto: closed
-
ABNT
BERTO, Gabriela L e ARANTES, Valdeir. Kinetic changes in cellulose properties during defibrillation into microfibrillated cellulose and cellulose nanofibrils by ultra-refining. International journal of biological macromolecules, v. 127, n. 15, p. 637-648, 2019Tradução . . Disponível em: https://doi.org/10.1016/j.ijbiomac.2019.01.169. Acesso em: 02 maio 2024. -
APA
Berto, G. L., & Arantes, V. (2019). Kinetic changes in cellulose properties during defibrillation into microfibrillated cellulose and cellulose nanofibrils by ultra-refining. International journal of biological macromolecules, 127( 15), 637-648. doi:10.1016/j.ijbiomac.2019.01.169 -
NLM
Berto GL, Arantes V. Kinetic changes in cellulose properties during defibrillation into microfibrillated cellulose and cellulose nanofibrils by ultra-refining. [Internet]. International journal of biological macromolecules. 2019 ;127( 15): 637-648.[citado 2024 maio 02 ] Available from: https://doi.org/10.1016/j.ijbiomac.2019.01.169 -
Vancouver
Berto GL, Arantes V. Kinetic changes in cellulose properties during defibrillation into microfibrillated cellulose and cellulose nanofibrils by ultra-refining. [Internet]. International journal of biological macromolecules. 2019 ;127( 15): 637-648.[citado 2024 maio 02 ] Available from: https://doi.org/10.1016/j.ijbiomac.2019.01.169 - Single-Step Fiber Pretreatment with Monocomponent Endoglucanase: Defibrillation Energy and Cellulose Nanofibril Quality.
- Endoglucanase effects on energy consumption in the mechanical fibrillation of cellulose fibers into nanocelluloses
- Clonagem, expressão e purificação de glicosil hidrolases (GH5 e GH45) provenientes do fungo Gloeophyllum trabeum e estudo da ação das proteínas como auxiliares na hidrólise de polissacarídeos
- Effect of chemical treatment of pineapple crown fiber in the production, chemical composition, crystalline structure, thermal stability and thermal degradation kinetic properties of cellulosic materials.
- Nanocellulose from lignocellulosic biomass
- Pré-tratamentos bioquímicos para isolamento de celulose nanofibrilada
- Pré-tratamentos bioquímicos para isolamento de celulose nanofibrilada
- Effect of the chemical treatment sequence on pineapple peel fiber: chemical composition and thermal degradation behavior
- Endoglucanase pretreatment aids in isolating tailored-cellulose nanofibrils combining energy saving and high-performance packaging
- Integration of the cellulose nanoccrystals isolation process, through enzymatic hydrolysis to the production of sugar for 2G ethanol from sugarcane bagasse.
Informações sobre o DOI: 10.1016/j.ijbiomac.2019.01.169 (Fonte: oaDOI API)
How to cite
A citação é gerada automaticamente e pode não estar totalmente de acordo com as normas