Using Undigested Biomass Solid Leftovers from the Saccharification Process to Integrate Lignosulfonate Production in a Sugarcane Bagasse Biorefinery (2022)
- Authors:
- USP affiliated authors: FERRAZ, ANDRÉ LUIS - EEL ; HEINZ, OTTO LUCAS - EEL
- Unidade: EEL
- DOI: 10.1021/acssuschemeng.2c01274
- Subjects: CELULOSE; LIGNINA; CALDO DE CANA; MONOSSACARÍDEOS; SACARIFICAÇÃO
- Keywords: biorefinery; cellulases; lignin; lignosulfonates; monosaccharides; saccharification leftovers; sugarcane; 2D-NMR
- Agências de fomento:
- Language: Inglês
- Abstract: Innovative schemes for lignocellulosic biomass refining could optimize the chemical use and biomass conversion efficiency, providing diversified biorefinery products. A new biorefinery scheme used mild alkaline-sulfite chemithermomechanical processing to pretreat sugarcane bagasse, producing highly digestible solids and diluted lignosulfonates in the black pretreatment liquor. Most of the glucan and xylan contained in the pretreated solids were converted into monosaccharides by saccharification with commercial enzymes. The undigested biomass solids remaining from the saccharification process were recycled with the existing alkaline-sulfite black pretreatment liquor. The optimized reaction conditions (159 °C and 13% NaOH amendment in the liquor) enhanced the lignosulfonate concentration from 7.1 ± 0.3 to 33.5 ± 0.7 g/L. Mass balance for the process indicates that most of the original sugarcane bagasse lignin were split into lignosulfonates contained in the resulfonation liquor (57.3%) and in the enzymatic hydrolysate (16.2%). 2D-NMR analysis of a lignosulfonate fraction recovered by ultrafiltration confirmed that approximately 9–10% of all β-O-4′ alkyl–aryl ether substructures were α-sulfonated. The combined chemical characteristics of the prepared lignosulfonate suggested its suitability for use in several lignosulfonate applications.
- Source:
- Título do periódico: ACS Sustainable Chemistry & Engineering
- ISSN: 21680485
- Volume/Número/Paginação/Ano: v., n. , p.7576-7585, 2022
- Este periódico é de assinatura
- Este artigo NÃO é de acesso aberto
- Cor do Acesso Aberto: closed
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ABNT
HEINZ, Otto et al. Using Undigested Biomass Solid Leftovers from the Saccharification Process to Integrate Lignosulfonate Production in a Sugarcane Bagasse Biorefinery. ACS Sustainable Chemistry & Engineering, n. , p. 7576-7585, 2022Tradução . . Disponível em: https://doi.org/10.1021/acssuschemeng.2c01274. Acesso em: 02 maio 2024. -
APA
Heinz, O., Rencoret, J., del Río, J. C., & Ferraz, A. L. (2022). Using Undigested Biomass Solid Leftovers from the Saccharification Process to Integrate Lignosulfonate Production in a Sugarcane Bagasse Biorefinery. ACS Sustainable Chemistry & Engineering, ( ), 7576-7585. doi:10.1021/acssuschemeng.2c01274 -
NLM
Heinz O, Rencoret J, del Río JC, Ferraz AL. Using Undigested Biomass Solid Leftovers from the Saccharification Process to Integrate Lignosulfonate Production in a Sugarcane Bagasse Biorefinery [Internet]. ACS Sustainable Chemistry & Engineering. 2022 ;( ): 7576-7585.[citado 2024 maio 02 ] Available from: https://doi.org/10.1021/acssuschemeng.2c01274 -
Vancouver
Heinz O, Rencoret J, del Río JC, Ferraz AL. Using Undigested Biomass Solid Leftovers from the Saccharification Process to Integrate Lignosulfonate Production in a Sugarcane Bagasse Biorefinery [Internet]. ACS Sustainable Chemistry & Engineering. 2022 ;( ): 7576-7585.[citado 2024 maio 02 ] Available from: https://doi.org/10.1021/acssuschemeng.2c01274 - Produção integrada de monossacarídeos e lignosulfonatos a partir de bagaço de cana-de-açúcar
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Informações sobre o DOI: 10.1021/acssuschemeng.2c01274 (Fonte: oaDOI API)
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